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Cementite

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cementite [si′men‚tīt]
(metallurgy)
Fe3C A hard, brittle, crystalline compound occurring as lamellae or plates in steel. Also known as iron carbide.

Cementite 

an iron carbide, Fe3C; a phase and structural component of iron-carbon alloys (seeIRON-CARBON ALLOYS). Cementite has an orthorhombic crystal lattice. It is very hard and brittle and is slightly magnetic at temperatures up to 210°C. It is a metastable phase; the formation of the stable phase—graphite—is in many cases difficult. Cementite is precipitated from a melt consisting of austenite and ferrite. Depending on the crystallization conditions and subsequent treatment, it can have various forms, such as equiaxial grains, lattices along grain boundaries, and plates; it can also exhibit a Widmannstatten structure. Cementite is a constituent of the structural components of steel and cast iron—ledeburite, pearlite, bainite, and tempered sorbite.

REFERENCE

Bunin, K. P., and A. A. Baranov. Metallografiia. Moscow, 1970.


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By increasing the number of graphite nodules during solidification, the rate of release of latent heat due to graphite crystallization increases, and the end of freezing temperature is raised above the cementite liquidus line, preventing carbide formation.
Malleable iron castings result when hard, brittle cementite in white iron castings is transformed into tempered carbon or graphite in the form of rounded nodules or aggregate.
If we make an equivalence between steel and polypropylene, Austenite is equivalent to molten polypropylene, Ferrite and Cementite to [alpha]-monoclinic polypropylene, Martensite to the smectic form.
 
 
 
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