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chemical shift
(redirected from Chemical Shift Anisotropy)

   Also found in: Medical, Acronyms, Wikipedia 0.01 sec.
chemical shift [′kem·i·kəl ′shift]
(physical chemistry)
Shift in a nuclear magnetic-resonance spectrum resulting from diamagnetic shielding of the nuclei by the surrounding electrons.


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The Magic Angle Spinning (MAS) of the samples leads to the complete averaging of the chemical shift anisotropy (CSA) and dipolar interactions: it follows that highly resolved spectra can be recorded even for powdered samples.
 
 
 
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