Chlorites


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Chlorites

 

a group of widely occurring minerals; the hydrous meta-aluminumosilicates of Mg and Fe, with a layered, mica-like crystal structure. The chemical composition of chlorites is (Mg, Fe2+) · [AlSi3O10(OH)2] · 3(Mg, Fe)(OH)2. Al isomorphically substitutes for Si within the limits Si7Al═Si4Al4 and for Mg within the limits Mg11 Al═Mg4Al4. Mg2+ may be entirely replaced by iron Fe2+ and Fe3+ and also partially by Mn2+, Cr, Ni, Ti, Li, or other elements. Scientists distinguish trioctahedral chlorites, dioctahedral chlorites, and chlorites with partially or completely disordered crystal structures. The layered crystal structure of chlorites is responsible for the great abundance of polymorphic modifications, or polytypes. Mixed layered formations of the chlorite-montmorillonite and chlorite-vermiculite (corrensite) types frequently occur. A distinction is also made between orthochlorites (unoxidized, containing not more than 4 percent Fe2O3) and leptochlorites (oxidized, rich in Fe2O3) according to the Fe2+/Fe3+ ratio.

Orthochlorites constitute a large group of minerals, which differ in the total iron content, that is, the magnitude of the Fe/(Fe + Mg) ratio of the octahedral layers, and in the Si/Al ratio in the tetrahedrons. The following orthochlorites are distinguished: (1) magnesium orthochlorites (in order of increasing Si content), which include corundophilite, sheridanite, clinochlore, penninite, and talc chlorite; (2) iron-magnesium orthochlorites, which include ripidolite, pycnochlorite, and diabantite; and (3) iron orthochlorites, which include pseudothuringite, daphnite, and brunsvigite. Leptochlorites include thuringite, chamosite, and delessite. There are also manganese chlorites (pennanite and gonyerite), chromium chlorites (kámmererite and kotschubeite), lithium chlorites (cookeite), and other types of chlorites.

A precise identification of chlorites is possible using X-ray diffraction analysis, electrographic methods, and thermal analysis. Chlorites crystallize in the monoclinic or triclinic system. They have a mica-like, lamellar pseudohexagonal crystal habit and exhibit perfect cleavage. The hardness on Mohs’ scale varies from 1.5 to 2.5. Chlorite lamellae are flexible but not elastic. The density of the minerals range from 2,600 to 3,300 kg/m3. Chlorites occur in the form of lamellar, plumose, globular, or cryptocrystalline oolitic aggregates. Their color usually ranges from light green to dark green, although white, yellow (low-iron), pink, red violet (containing Cr and Mn), and black (iron chlorite) varieties are also known.

Orthochlorites are important rock-forming minerals of the greenschists, which are rocks of the initial stages of regional metamorphism. They are characteristic of altered rocks lying near to ores in hydrothermal deposits and of altered lavas of volcanic regions. The processes of chloritization are widespread in nature and occur at relatively low temperatures. Chlorites often occur as alteration products of higher temperature iron-magnesium silicates, such as biotite and the amphiboles; they also replace scapolites, plagioclases, garnets, vesuvianite, staurolite, and many other minerals, with the formation of pseudomorphs. Chlorites appear in large quantities, together with talc and serpentine, during the hydrothermal transformation of ultrabasic rocks, volcanic tuffs, shales, and sometimes even dolomites. They are often present in ore-bearing quartz veins and aureoles around veins. Lithium chlorites are found in rare metal pegmatites, chromium chlorites occur in chromite deposits, and nickel chlorites form during the alteration of certain basic igneous rocks. The leptochlorites thuringite and chamosite are primarily sedimentary in origin. They sometimes form large bodies of industrial importance, such as the iron ores in the Urals, Thuringia, and the Lorraine.

REFERENCES

Serdiuchenko, D. P. Khlority, ikh khimicheskaia konstitutsiia i klassifikatsiia. Moscow, 1953. (Tr. In-ta geologich. nauk AN SSSR, fasc. 140.)
Kepezhinskas, K. B. Statisticheskii analiz khloritov i ikh parageneticheskietipy. Moscow, 1965.
Deer, W. A., R. A. Howie, and J. Zussman. Porodoobrazuiushchie mineraly, vol. 3: Listovye silikaty. Moscow, 1966. (Translated from English.)
Rostov, I. Mineralogiia. Moscow, 1971. (Translated from English.)
Godovikov, A. A. Mineralogiia. Moscow, 1975.

A. M. PORTNOV and L. G. FEL’DMAN

References in periodicals archive ?
Soil pH was calculated for the laboratory experiment soils to determine if fire-altered pH was a mechanism for chlorite weathering at depth.
The lack of correlation between field and laboratory data on chlorite peak relative intensities and increasing clay-sized particles at depth makes it unclear at this time if altered pH of pooling rainwater is the mechanism for chlorite weathering at depth.
Chlorite weathering at depth in soils containing a restrictive layer, under the influence of fire, is likely dependent on ash chemistry rather than on the degree of soil heating, typically the cause of clay alterations attributed to fire at the surface.
The study of chlorites removal on GAC filters conducted in Fortore pilot plant showed very high efficiency of the process (>95%) up to 4000 bed volumes (Fig.
It means that GAC filters in Fortore pilot plant should require more regular backwashing to improve its efficiency of chlorites removal.