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chemical shift
(redirected from Deshielding)

   Also found in: Medical, Wikipedia 0.02 sec.
chemical shift [′kem·i·kəl ′shift]
(physical chemistry)
Shift in a nuclear magnetic-resonance spectrum resulting from diamagnetic shielding of the nuclei by the surrounding electrons.


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The substitution of one HEMA unit by one MA unit in an MA centered sequence gives rise to a small deshielding effect of the C=0 amide group of the MA central unit, with a shift of the corresponding signal to a lower field (higher 6).
 
 
 
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