Hexamethylenediamine

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hexamethylenediamine

[‚hek·sə′meth·ə‚lēn′dī·ə‚mēn]
(organic chemistry)
H2N(CH2)6NH2 Colorless solid boiling at 205°C; slightly soluble in water, alcohol, and ether; used to make nylon and other high polymers.

Hexamethylenediamine

 

the organic compound NH2(CH2)6NH2; colorless crystals. Melting point, 42° C; boiling point, 204°-205° C; readily soluble in water, alcohol, ether, and other organic solvents; distilled by steam.

With prolonged exposure, hexamethylenediamine vapors can cause disturbances of the central and autonomic nervous systems and other disorders in man. Hexamethylenediamine is a very important intermediate in the production of polyamide fibers (nylon). Worldwide production of the compound approaches several hundred thousand tons per year. A widespread industrial method for hexamethylenediamine production consists of adipodinitrile reduction on copper-cobalt catalysts (125° C, 60-62.5 meganewtons per sq m, 600-625 kilograms-force per sq cm), cobalt on silica gel, or other catalysts:

N≡C−(CH2)4−C≡N + 4H2→NH2(CH2)6NH2

References in periodicals archive ?
DAO is especially active towards diaminopentane and diaminohexane.
Layered silicate polymer NC were prepared from the following components: 60 wt% aqueous solution of 1,6 diaminohexane (HMDA) from Acros Organics, adipoyl chloride (AdCl) from Sigma-Aldrich (purum [greater than or equal to] 99%), toluene from Fisher Scientific, distilled water, Cloisite[R] 20A MMT treated with dimethyl dihydrogenated tallow, and Cloisite[R] 30B MMT treated with methyl, tallow, bis-2-hydroxyethyl quaternary ammonium salts from Southern Clay Products, [Na.