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diastereomer |
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As a result, a new chiral center is formed, and in respect to the given chirality in the backbone, the two possible N-configurations result in two possible diastereomers. At temperatures above 160[degrees]C, thermal rearrangements of the diastereomers can occur. Gilliland, Structure of the Xenobiotic Substrate Binding Site of a Glutathione S-Transferase as Revealed by X-ray Crystallographic Analysis of Product Complexes with the Diastereomers of 9-(S-Glutathionyl)-10-Hydroxy-9,10-Dithydrophenanthrene, Biochemistry 33 (5), 1043-1052 (1994). |
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