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disproportionation

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disproportionation [‚dis·prə‚pȯr·shə′nā·shən]
(chemistry)
The changing of a substance, usually by simultaneous oxidation and reduction, into two or more dissimilar substances.
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Disproportionation of the macromolecular carbon-centered radicals can also lead to formation of terminal double bonds in the scissioned chains.
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In addition, steric hindrance would favor termination by disproportionation as opposed to coupling which would also result in a decrease in [M.
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In the process, the hypophosphite molecule goes through some tricky disproportionation maneuvers, and some of the phosphorous gets trapped in the metal deposit, too.
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