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Electron capture |
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Electron capture The process in which an atom or ion passing through a material medium either loses or gains one or more orbital electrons. In the passage of charged particles (defined here as nuclei having more or less than Z atomic electrons, where Z is the atomic number) through matter, the capture (and loss) of electrons is an important process in the slowing down of the particles and therefore has a strong influence on their range. Thus a neutral hydrogen atom loses only about half as much energy per centimeter as the positively charged proton in passing through matter consisting of light elements. For the ordinary charged particles (alpha particles and protons) the capture process is important only at low energies, when the particle velocity is of the order of electron velocities in the stopping material, and thus is important at the end of the range. For fission fragments, however, which initially have a large excess of positive charges, electron capture occurs immediately and continues throughout the slowing-down process. This fact causes the energy-loss mechanisms at the latter part of the range to be different for fission fragments and protons or alpha particles. See Nuclear fission The nuclear capture of electrons (K capture) occurs by a process quite different from atomic capture and is in fact a consequence of the general beta interaction. This general interaction includes ß - decay (the oldest known beta transformation and hence the name), ß + decay (or positron decay), and K capture, the latter so called because the electron captured by the nucleus is taken from the K shell (the shell nearest the nucleus) of atomic electrons. A second-order process, called L capture, can also occur, in which (to speak pictorially and thus somewhat imprecisely) an s electron (from the K shell) is captured with the simultaneous transition of a p electron (from the L shell) to the K shell with the emission of gamma radiation. See Radioactivity How to thank TFD for its existence? Tell a friend about us, add a link to this page, add the site to iGoogle, or visit webmaster's page for free fun content. |
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The new method combines two different ionic dissociation methods, collision induced dissociation (CID) and electron capture dissociation (ECD), to analyze proteins thoroughly by quickly switching the dissociation methods. An aliquot of transformer oil from the drum of the Exxon Univolt 60 transformer oil was examined for traces of PCBs as would be evident by capillary gas chromatography with electron capture detection (GC-ECD). The sampling effort by 23 labs measured dioxins with mass spectrometry and quantified PCBs using gas chromatographic techniques along with electron capture or mass spectrometry. |
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