Franck-Rabinowitch hypothesis

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Franck-Rabinowitch hypothesis [¦fräŋk rə′bin·ə‚wich hī‚päth·ə·səs]

(physical chemistry)

The hypothesis that the decreased quantum efficiencies of certain photochemical reactions observed in the dissolved or liquid state are due to the formation of a cage of solvent molecules around the molecule which has been excited by absorption of a photon.

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