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Gibbs-Duhem equation
(redirected from Gibbs-Duhem relation)

    Also found in: Wikipedia 0.03 sec.
Gibbs-Duhem equation [¦gibz ′dü·əm i‚kwā·zhən]
(physical chemistry)
A relation that imposes a condition on the composition variation of the set of chemical potentials of a system of two or more components,whereSis entropy,Tabsolute temperature,Ppressure,nithe number of moles of theith component, and μiis the chemical potential of theith component. Also known as Duhem's equation.


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