Hofmann amine separation

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Hofmann amine separation [′häf·mən ′am‚ēn ‚sep·ə‚rā·shən]

(organic chemistry)

A technique to separate a mixture of primary, secondary, and tertiary amines; they are heated with ethyl oxalate; there is no reaction with tertiary amines, primary amines form a diamide, and the secondary amines form a monoamide; when the reaction mixture is distilled, the mixture is separated into components.

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