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hydroboration

   Also found in: Wikipedia 0.01 sec.
hydroboration [¦hī·drō·bə′rā·shən]
(organic chemistry)
The process of producing organoboranes by the addition of a compound with a B-H bond to an unsaturated hydrocarbon; for example, the reaction of diborane ion with a carbonyl compound. Also known as boration.


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[FIGURE 1 OMITTED] RESULTS AND DISCUSSION In the light of the information referred to above we made an attempt to obtain diketones 2 and 3 directly from lactone 1 by hydroboration (Scheme 2).
Primary amine functionalization was completed in refluxing THF by performing hydroboration with 9-BBN followed by amination with hydroxylamine-o-sulfonic acid.
 
 
 
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