Ionization potential (redirected from Ionization enthalpy)

ionization potential

 or ionization energy

Amount of energy required to remove an electron from an isolated atom or molecule. There is an ionization potential for each successive electron removed, though that associated with removing the first (most loosely held) electron is most commonly used. The ionization potential of an element is a measure of its ability to enter into chemical reactions requiring ion formation or donation of electrons and is related to the nature of the chemical bonding in the compounds formed by elements. See also binding energy, ionization.

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Ionization potential

The potential difference through which a bound electron must be raised to free it from the atom or molecule to which it is attached. In particular, the ionization potential is the difference in potential between the initial state, in which the electron is bound, and the final state, in which it is at rest at infinity.

The ionization potential for the removal of an electron from a neutral atom other than hydrogen is more correctly designated as the first ionization potential. The potential associated with the removal of a second electron from a singly ionized atom or molecule is then the second ionization potential, and so on.