iron (redirected from Iron (mineral))

iron, metallic chemical element; symbol Fe [Lat. ferrum]; at. no. 26; at. wt. 55.847; m.p. about 1,535°C;; b.p. about 2,750°C;; sp. gr. 7.87 at 20°C;; valence +2, +3, +4, or +6. Iron is biologically significant. Because iron is a component of hemoglobin, a red oxygen-carrying pigment of the red blood cells of vertebrates, iron compounds are important in nutrition; one cause of anemia is iron deficiency. For the history of the use of iron, see Iron Age.

Properties

Iron is a lustrous, ductile, malleable, silver-gray metal found in Group 8 of the periodic table. It is known to exist in four distinct crystalline forms (see allotropy). The most common is the α-form, which is stable below about 770°C;, and has a body-centered cubic crystalline structure; it is often called ferrite. Iron is attracted by a magnet and is itself easily magnetized (see magnetism). It is a good conductor of heat and electricity. It displaces hydrogen from hydrochloric or dilute sulfuric acid, but becomes passive (loses its normal chemical activity) when treated with cold nitric acid.

Compounds

Iron forms such compounds as oxides, hydroxides, halides, acetates, carbonates, sulfides, nitrates, sulfates, and a number of complex ions. It is chemically active and forms two major series of chemical compounds, the bivalent iron (II), or ferrous, compounds and the trivalent iron (III), or ferric, compounds. Ferrous sulfate heptahydrate, FeSO₄·7H₂O, sometimes called green vitriol, is a compound formed by the reaction of dilute sulfuric acid (formerly called oil of vitriol) with metallic iron; it is used in the manufacture of ink, in dyeing, and as a disinfectant. Ferric chloride hexahydrate, FeCl₃·6H₂O, is a yellow-brown crystalline compound used as a mordant in dyeing and as an etching compound. Ferric oxide, Fe₂O₃, is a reddish-brown powder used as a paint pigment and in abrasive rouges. Prussian blue, KFe₂(CN)₆, is a pigment containing the ferrocyanide complex ion. Iron rusts readily in moist air, forming a complex mixture of compounds that is mostly a ferrous-ferric oxide with the composition Fe₃O₄.

Natural Occurrence

Iron is an abundant element in the universe; it is found in many stars, including the sun. Iron is the fourth most abundant element in the earth's crust, of which it constitutes about 5% by weight, and is believed to be the major component of the earth's core. Iron is found distributed in the soil in low concentrations and is found dissolved in groundwaters and the ocean to a limited extent. It is rarely found uncombined in nature except in meteorites, but iron ores and minerals are abundant and widely distributed.

The principal ores of iron are hematite (ferric oxide, Fe₂O₃) and limonite (ferric oxide trihydrate, Fe₂O₃·3H₂O). Other ores include siderite (ferrous carbonate, FeCO₃), taconite (an iron silicate), and magnetite (ferrous-ferric oxide, Fe₃O₄), which often occurs as a white sand. Iron pyrite (iron disulfide, FeS₂) is a crystalline gold-colored mineral known as fool's gold. Chromite is a chromium ore that contains iron. Lodestone is a form of magnetite that exhibits natural magnetic properties.

Production and Refining

Iron is produced in the United States chiefly from oxide ores. For many years rich hematite ores were produced by open-pit mining in the Mesabi Range near Lake Superior. However, these ores have been largely depleted, and iron is now produced from low-grade ores that are treated to improve their quality; this process is called beneficiation. Iron ores are refined in the blast furnace. The product of the blast furnace is called pig iron and contains about 4% carbon and small amounts of manganese, silicon, phosphorus, and sulfur. About 95% of this iron is processed further to make steel, often by the open-hearth process or the Bessemer process, but more recently in the United States and other countries by the basic oxygen process or by an electric arc furnace. The balance is cast in sand molds into blocks called pigs. It is further processed in iron foundries (see casting).

Cast Iron

Cast iron is made when pig iron is remelted in small cupola furnaces (similar to the blast furnace in design and operation) and poured into molds to make castings. It usually contains 2% to 6% carbon. Scrap iron or steel is often added to vary the composition. Cast iron is used extensively to make machine parts, engine cylinder blocks, stoves, pipes, steam radiators, and many other products. Gray cast iron, or gray iron, is produced when the iron in the mold is cooled slowly. Part of the carbon separates out in plates in the form of graphite but remains physically mixed in the iron. Gray iron is brittle but soft and easily machined. White cast iron, or white iron, which is harder and more brittle, is made by cooling the molten iron rapidly. The carbon remains distributed throughout the iron as cementite (iron carbide, Fe₃C). A malleable cast iron can be made by annealing white iron castings in a special furnace. Some of the carbon separates from the cementite; it is much more finely divided than in gray iron. A ductile iron may be prepared by adding magnesium to the molten pig iron; when the iron is cast the carbon forms tiny spherical nodules around the magnesium. Ductile iron is strong, shock resistant, and easily machined.

Wrought Iron

Wrought iron is commercially purified iron. In the Aston process, pig iron is refined in a Bessemer converter and then poured into molten iron silicate slag. The resulting semisolid mass is passed between rollers that squeeze out most of the slag. The wrought iron has a fibrous structure with threads of slag running through it; it is tough, malleable, ductile, corrosion resistant, and melts only at high temperatures. It is used to make rivets, bolts, pipes, chains, and anchors, and is also used for ornamental ironwork.

Bibliography

See W. H. Dennis, Metallurgy of the Ferrous Metals (1963) and Foundations of Iron and Steel Metallurgy (1967).

---

iron

Metallic chemical element, one of the transition elements, chemical symbol Fe, atomic number 26. Iron is the most used and cheapest metal, the second most abundant metal and fourth most abundant element in Earth's crust. It occurs rarely as a free metal, occasionally in natural alloys (especially in meteorites), and in hundreds of minerals and ores, including hematite, magnetite, limonite, and siderite. The human body contains about one-sixth of an ounce (4.5 g) of iron, mostly in hemoglobin and its precursors; iron in the diet is essential to health. Iron is ferromagnetic (see ferromagnetism) at ordinary temperatures and is the only metal that can be tempered (see tempering). Its uses in steels of various types, as well as in cast and wrought iron (collectively, “ferrous metals”), are numerous. Alteration of its properties by impurities, especially carbon, is the basis of steelmaking. Iron in compounds usually has valence 2 (ferrous) or 3 (ferric). Ferrous and ferric oxides (FeO and Fe₂O₃, respectively) are used as pigments and the latter as jewelers' rouge. Rust is ferric oxide containing water; ferric oxide is widely used as a magnetic recording material in computer data-storage devices and magnetic tapes. Ferrous and ferric sulfates and chlorides are all of industrial importance as mordants, reducing agents, flocculating agents, or raw materials and in inks and fertilizers.

---

iron

1. 

a. a malleable ductile silvery-white ferromagnetic metallic element occurring principally in haematite and magnetite. It is widely used for structural and engineering purposes. See also steel, cast iron, wrought iron, pig iron. Symbol: Fe; atomic no.: 26; atomic wt.: 55.847; valency: 2,3,4, or 6; relative density: 7.874; melting pt.: 1538?C; boiling pt.: 2862?C

b. (as modifier): iron railings

2. any of certain tools or implements made of iron or steel, esp for use when hot

3. an appliance for pressing fabrics using dry heat or steam, esp a small electrically heated device with a handle and a weighted flat bottom

4. any of various golf clubs with narrow metal heads, numbered from 1 to 9 according to the slant of the face, used esp for approach shots

5. an informal word for harpoon

---

iron - Hardware, especially older and larger hardware of mainframe class with big metal cabinets housing relatively low-density electronics (but the term is also used of modern supercomputers). Often in the phrase big iron. Oppose silicon. See also dinosaur.