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metallation

   Also found in: Wikipedia 0.01 sec.
metallation [‚med·ə′lā·shən]
(organic chemistry)
The direct replacement of a hydrogen atom by a metal atom in an organic molecule to form a carbon-metal bond.


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49) Experimental study of metallation mechanism in TMEDA/metal alkoxide modified anionic polymerization.
[[Eta]] was little affected below about 70% amide group metallation, but was diminished above 70%, as shown in Fig.
Metal Chemistry of Porphyrinoids summarizes these recent synthetic developments, particularly in respect of metallation strategies for freebase porphyrinoids, as well as progress towards applications in areas such as sensor and optical materials, catalysis and medicine.
 
 
 
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