chloramine

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Related to Monochloramine: Dichloramine

chloramine:

see hydrazinehydrazine
, chemical compound, formula NH2NH2, m.p. 1.4°C;, b.p. 113.5°C;, specific gravity 1.011 at 15°C;. It is very soluble in water and soluble in alcohol.
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Chloramine

 

any one of a group of chloroderivatives of ammonia (inorganic chloramines) or amines (organic chloramines), whose molecules contain a chlorine atom bonded to nitrogen. (For a discussion of inorganic chloramines, seeNITROGEN CHLORIDE.)

Organic chloramines are liquids or solids, with a pungent odor that irritates the upper respiratory tract. They include the liquids N-chlorodimethylamine, (CH3)2NCl, which boils at 46°C, N,N-dichloromethylamine, CH3NCl2, which boils at 58°–60°C, and N,N-dichloroethylamine, C2H5NCl2, and N-chlorodiethylamine, (C2H5)2NCl, which boils at 91°C. Hexachloromelamine, whose structural formula is

is a yellow crystalline compound with a melting point of 149°C.

Chloramines decompose in the presence of water, including atmospheric moisture, with the formation of an amine and hypochlorous acid, HOCl. Solutions of chloramines in organic solvents are rather stable. Chloramines are produced by the action of chlorine or hypochlorous acid on amines and amine salts.

The term “chloramine” is often used to denote any N-chloro-derivative of the amides of organic and inorganic acids. Chloramides and dichloramides of aromatic sulfonic acids have found great practical use. Chloramine-B, C6H5SO2NNaCl · 3H2O (the sodium salt of the N-chloramide of benzenesulfonic acid), and chloramine-T, (CH3)C6H4SO2NNaCl · 3H2O (the sodium salt of the N-chloramide of p-toluenesulfonic acid), are colorless crystals with a melting point of 180°–185°C and 175°–180°C, respectively; they are readily soluble in water and ethanol. Dichloramine-B (N,N-dichloro-benzenesulfonamide) and dichloramine-T (N,N-dichloro-p-toluenesulfonamide) are crystals with an odor of chlorine and a melting point of 69°–72°C and 80°–83°C, respectively; they are insoluble in water but soluble in organic solvents, usually dichloroethane.

Chloramines have oxidizing and chlorinating properties and consequently are used in analytical chemistry and in industry, for example, in the textile industry to bleach fabrics; they are also used as decontaminants. In medicine, chloramines, mainly chloramine-B, are used as antiseptics. Chloramine-B, which contains 25–29 percent active chlorine, is also used as a deodorizer and spermatocide. A 0.25–0.5 percent solution of chloramine-B is used to disinfect hands, while a 1–5 percent solution of chloramine-B, chloramine-T, or dichloramine are used to decontaminate utensils and excretions of patients with intestinal and respiratory infections. Chloramines are also used for chlorination of water (Pantocid tablets), treatment of infected wounds, and decontamination of hands and nonmetallic equipment.

References in periodicals archive ?
Its Henry's Law constant is approximately 100 times that of monochloramine.
Ralisation dune installation de traitement biocide (CTE) par injection de monochloramine Belleville.
So, some utilities have switched to monochloramine, a compound of chlorine, nitrogen, and hydrogen.
The monochloramine and hypochlorous acid solutions were roughly equivalent in their respective impacts.
Contract notice: C4525c0620 - realization of biocide treatment facilities (cte) by injection of monochloramine in dampierre.
The measurement capabilities of the analyzer include single or dual-measurement of pH, ORP, ISE (Ion-Selective Electrodes), resistivity/conductivity, percent concentration, total chlorine, free chlorine, monochloramine, dissolved oxygen, gaseous oxygen, dissolved ozone, turbidity, pulse flow, and temperature.
Monochloramine disinfection of municipal water supplies is associated with decreased risk for Legionnaires' disease (36,37).
To complement the exposure assessment, we evaluated the mutagenicity of the pool waters in the Salmonella mutagenicity assay and screened for DBPs, comprehensively identifying most DBPs detected and quantifying a few targeted DBPs and disinfectant species (THMs, chlorine, monochloramine, dichloramine, and trichloramine) in the pool waters and in the air phase above the water (THMs and trichloramine).
Trichloramine is more volatile than monochloramine and dichloramine and is released into the air more readily.
A 1979 change in the Safe Drinking Water Act has encouraged many municipalities to switch their disinfectant from free chlorine to monochloramine.
The dispersion and survival of VTEC 0157 will be analysed by using a continuous-culture model of biofilm growing on a specific tile surface such as copper, galvanized iron, mild steel, stainless steel, bitumen-painted steel, or new materials such as polyethylene or PVC after classical disinfection treatments with chlorine and monochloramine at 5, 15 and 25rC.