Olivine (redirected from Olivine structure)

olivine (ŏlĭv`ēn), an iron-magnesium silicate mineral, (Mg,Fe)₂SiO₄, crystallizing in the orthorhombic system. It is a common constituent of magnesium-rich, silica-poor igneous rocks; metamorphism of some high magnesium sediments also can form olivine. Dunite consists almost entirely of olivine. It also occurs in lunar rocks and meteorites. Olivine has a characteristic yellow-green to olive-green color, hence the name. Transparent olivine of good color can be cut into gemstones; the gem form is known as peridot. Sources of gem-quality olivine are St. John's Island in the Red Sea, Myanmar, and Arizona. Magnesium-rich olivine has a high melting point and is used in the manufacture of refractories. It was formerly called chrysolite.

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olivine

Any member of a group of common magnesium, iron silicate minerals. Olivines occur in many igneous rocks and are a major constituent of the Earth's upper mantle. They also have been found in some lunar rocks and in many meteorites. Olivine forms yellow to greenish yellow crystals and is sometimes used in making bricks. Transparent green olivine (precious olivine) is called peridot.

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olivine [′äl·ə‚vēn]

(mineralogy)

(Mg,Fe₂)SiO₄A neosilicate group of olive-green magnesium-iron silicate minerals crystallizing in the orthorhombic system and having a vitreous luster; hardness is 6½-7 on Mohs scale; specific gravity is 3.27-3.37.

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Olivine 

(also peridot or chrysolite), a mineral of the neso-silicate class; the main representative of the olivine group. The olivine group includes forsterite, Mg₂[SiO₄]; olivine, (Mg,Fe)₂[SiO₄]; fayalite, Fe₂[SiO₄]; tephroite, Mn₂[SiO₄]; knebelite, (Fe,Mn)₂[SiO₄]; and monticellite, CaMg[SiO₄].

The minerals of the olivine group differ from one another in both properties and composition. They crystallize in the ortho-rhombic system to form tabular or prismatic crystals. The olivine structure is composed of isolated tetrahedral SiO₄^4- groups and of Mg²⁺ and Fe²⁺ cations surrounded by six oxygen ions. The structural distribution of magnesium and iron, as determined by Mössbauer spectra, serves as a geothermometer. Olivine has imperfect cleavage; its hardness on Mohs’ scale is 6.5–7.0, and its density is 3,200–4,400 kg/m³, depending on the number of heavy iron and manganese atoms per molecule. Its color varies from yellowish green to olive green; sometimes the mineral is colorless.

Olivine is widespread in nature as a rock-forming mineral in ultrabasic and basic rocks, such as dunites, peridotites, olivine gabbros, diabases, and basalts, including lunar basalt. The olivine structure rearranges to form a spinel-type lattice under high pressure (130–160 kilobars). The effect of hydrothermal solutions readily alters olivine into serpentine and sometimes also to talc. On the earth’s surface, olivine decomposes to yield magne-site, hydrous iron oxides, and opal. Transparent olivine crystals, or chrysolites, are precious stones.

REFERENCE

Mineraly: Spravochnik, vol. 3, fasc. 1. Moscow, 1972.