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Understanding Organometallic Reaction Mechanisms and Catalysis: Computational and Experimental Tools
Smalley Institute, Tour took an interest in organometallic reaction development, and experimented heavily with carbon nanotubes, molecular electronics and nanomachines.
The file contains organic and organometallic reaction information derived from the weekly printed information service Cheminform.
Artificial metalloenzymes combine attractive features of both homogeneous catalysts and enzymes, including the possibility to genetically optimize the catalytic performance of new-to-nature organometallic reactions.
Ulrich Fekl received his PhD (summa cum laude) in 2000 from the University of Erlangen-Niirnberg, Germany under the supervision of Rudi van Eldik, for research on mechanisms of inorganic and organometallic reactions.
Acylation, alkylation, alkyl lithium reactions, amidation, bromination, chlorination, cyclization, decarboxylation, electrochemistry, electrophilic substitution, esterification, fluoride exchange, hydrogenation, nucleophilic substitutions, organometallic reactions, oxidations, palladium catalyzed carbonylation, phase transfer catalysis, photochemistry, reductions, sulfonation, vapor phase catalysis.
Required Mass Spectrometer having a linear ion trap coupled with electrospray ionization will be used to study the reaction intermediates of organic and organometallic reactions.
Electrochemical/sonoelectrochemical synthesis and conversion in green media (aqueous media/microemulsions, ionic liquids, and super critical fluids) using renewable energy: biomass conversion; electrocatalytic hydrogenation for chemoselective electrohydrogenations; electrocatalytic organometallic reactions.
Advantages and limitations of organometallic reactions in aqueous media
In his research, Snieckus has devised new organometallic reactions based on lithium and transition metal catalytic reactions which, aside from having fundamental value, have had considerable impact in the pharmaceutical and agrochemical industries for the production of drugs, plant-protection agents, and liquid crystals.
New Ligands for Enantioselective Catalysis of Organometallic Reactions -- V.
Investigations of the effect of high pressure on organic and organometallic reactions form part of Keay's projects.