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pseudopotential

   Also found in: Wikipedia 0.01 sec.
pseudopotential [‚sü·də·pə′ten·chəl]
(solid-state physics)
The common effective potential for electrons in a crystal lattice that is calculated in the orthogonalized plane-wave method and in the pseudopotential method, and that is relatively weak (except for diffracted electrons) because the electrons are moving rapidly past the atoms in the lattice.


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More ab initio theories directly calculate the full electronic states of the system, typically calculating the contribution of each atom to the electronic potential self-consistently within density functional or pseudopotential theory (see for example A.
Approximate methods are treated next, starting with spin separation in the Dirac equation, and proceeding to the Foldy-Wouthuysen, Douglas-Kroll, and related transformations, Breit-Pauli and direct perturbation theory, regular approximations, matrix approximations, and pseudopotential and model potential methods.
 
 
 
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