ketopyrans, heterocyclic compounds, oxo derivatives of pyrans. The simplest pyrones are α-pyrone, or coumalin, a colorless liquid with the odor of new-mown hay (boiling point, 206°-209°C), and γ-pyrone, colorless crystals (melting point, 31°–32°C).
Pyrones are highly reactive. For example, they react with ammonia and primary amines and are reduced readily; α-pyrone enters into the Diels-Alder reaction. Pyrones may be produced by decarboxylation of their derivatives, pyronecarboxylic acids (coumalic and chelidonic acids, respectively). Pyrone derivatives are widespread in nature. Tonka beans contain benzo-α-pyrone, or coumarin; opium contains meconic acid; and celandine sap contains chelidonic acid. Certain plant pigments are γ-pyrone derivatives.
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