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Quadrupole
(redirected from Quadrapole)

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quadrupole [′kwä·drə‚pōl]
(electromagnetism)
A distribution of charge or magnetization which produces an electric or magnetic field equivalent to that produced by two electric or magnetic dipoles whose dipole moments have the same magnitude but point in opposite directions, and which are separated from each other by a small distance.
(mathematics)
A mass distribution that has unequal components of the moment-of-inertia tensor along the three principal directions.

Quadrupole 

a system of charged particles whose total electric charge and electric dipole moment equal zero.

Figure 1. Examples of relative location of dipoles in a quadrupole

A quadrupole can be considered a set of two identical dipoles with the dipole moments equal in magnitude but opposite in direction and separated by a certain distance. At great distances R from the quadrupole, the field intensity of the quadrupole E decreases in inverse proportion to R to the fourth power (E∼ 1/R4). The relationship between E and the charges and their location is described in the general case by a set of five independent values that together constitute the quadrupole moment of the system. The quadrupole moment also determines the energy of a quadrupole in an external electric field. In the case described by Figure 1 the absolute value of the quadrupole moment is equal to 2ela, where e is the charge, 1 is the dimension of the dipoles, and a is the distance between the centers of the dipoles. A quadrupole is a second-order multipole.

REFERENCE

Landau, L. D., and E. M. Lifshits. Teoriia polia, 5th ed. Moscow, 1967, § 41.

G. IA. MIAKISHEV



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A combination of thin layer chromatography, ion-trapping gas chromarography-mas'-spectrometry, high pressure liquid chromatography, and quadrapole mass spectrometry was- used to characterize these oxidarion products, and the results reveal that a metabolite is produced coincident with MbH oxidation of PAPC, but not when Mb is used as the pro-oxidant.
Next the analyzer, of which there are also several to choose from, including: Quadrapole, Sector (Magnetic and/or Electrostatic), Time-of-Flight (TOF) and Ion Cyclotron Resonance (ICR), separates the ions of different masses.
QIAquick 96 PCR purification cartridges (Qiagen, Hilden, Germany, with modified binding and wash buffers) were used to remove unincorporated primers before tags were decoupled from amplification products by UV photolysis in a flow cell and analyzed in a quadrapole mass spectrometer by using positive-mode atmospheric pressure chemical ionization (APCI-MS, Agilent Technologies, Palo Alto, CA, USA).
 
 
 
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