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selenoxide |
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selenoxide [‚sel·ə′näk‚sīd]
(organic chemistry) A group of organic selenium compounds with the general formula R2SeO. Want to thank TFD for its existence? Tell a friend about us, add a link to this page, add the site to iGoogle, or visit the webmaster's page for free fun content. |
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No references found | Subsequent treatment with hydrogen peroxide allows oxidative elimination via an intermediate selenoxide. It is only after four in situ chemical transformations (oxidation to the selenoxide, [2,3]-sigmatropic rearrangement, a second oxidation and loss of allyl alcohol) that the true catalyst (4) is generated (equation 1). Clive, Professor of Chemistry, Department of Chemistry, University of Alberta, Edmonton, AB Winner of the 2002 Alfred Bader Award in Organic Chemistry of the Canadian Society for Chemistry Member of CIC since 1978 Derrick Clive is internationally recognized for his discovery of the syn-elimination of selenoxides, associated cyclization reactions and free radical cyclization reactions. |
selenoxide |
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