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sigmatropic shift |
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sigmatropic shift [¦sig·mə¦träp·ik ′shift]
(organic chemistry) A rearrangement reaction that consists of the migration of a sigma bond (that is, the sigma electrons) and the group of atoms that are attached to it from one position in a chain or ring into a new position. Want to thank TFD for its existence? Tell a friend about us, add a link to this page, add the site to iGoogle, or visit the webmaster's page for free fun content. |
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