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Sommerfeld law for doublets

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Sommerfeld law for doublets [′zȯm·ər‚felt ′lȯ fər ′dəb·ləts]
(atomic physics)
According to the Bohr-Sommerfeld theory, the splitting in frequency of regular or relativistic doublets is α2R(Z- σ)4/n3(l+ 1), where α is the fine structure constant,Ris the Rydberg constant of the atom,Zis the atomic number, σ is a screening constant,nis the principal quantum number, andlis the orbital angular momentum quantum number.


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