This kind of observation from the objective measurement of pH comes to strengthen the model of the colloid particle protection shield, which is acting through the mechanism of steric hindrance
rather than ionic colloid protection, although it is obviously necessary to do additional work and provide more details in its support.
As shown in the tridimensional structural model of FVIII, the cysteine residue may cause a steric hindrance
To maintain minimum steric hindrance
between two hydrazides in the complex and hence greater stability, the configuration of hydrazides in complexes is proposed to be trans .
A primary finding of the molecular simulation results is that the steric hindrance
and neighboring molecule effects of reactive moieties on monomers can cause heats of reaction to change up to 17% for urethane-forming reactions.
The limited steric hindrance
of the methyl groups favors the ductility of the resin, especially if compared with the cumbersome epoxy derivatives, allowing the deposition of thick layers.
The high stability is due to the electrostatic repulsive force and steric hindrance
of the PEI polymers against aggregation, and the high hydrophilicity of MPEG may also contribute to the stability.
In homogeneous medium, both acids give terminal double bond hydrogenation, producing the [alfa] and [beta] methyl position stereoisomers, favoring the [beta] isomer, probably due to less steric hindrance
during the Ru metal [pi] complex formation.
This critical value was consistently explained from the steric hindrance
effect of hIgG molecules.
It has also been shown from earlier studies that the steric hindrance
and anchimeric effect can play key roles in hydrolysis reaction.
The ionic form of the resin contributes to selectivity by virtue of its charge co-ordination stability, steric hindrance
with the pores of the resin, or through a combination of these factors.
This shows that complex has greater steric hindrance
involving free rotation of molecules.
Molecular recognition--and especially chiral recognition--is a central concept in molecular biology and many fields of organic chemistry, and is frequently thought to be dominated by steric hindrance
(perhaps taking Fischer's metaphor a little too literally).