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Van Vleck paramagnetism

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Van Vleck paramagnetism [van ′vlek ¦par·ə′mag·nə‚tiz·əm]
(quantum mechanics)
The paramagnetism of a collection of atoms, ions, or molecules, as computed by quantum theory; the atoms, ions, or molecules in a magnetic field are distributed among the various allowed energy levels according to a Boltzmann distribution, and the magnetization of the system is computed by finding the average component of angular momentum parallel to the field.


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