It could be seen that the byproducts of the whole reaction process included the unreacted raw materials such as dimethylamine ([(C[H.sub.3]).sub.2]NH) and allyl chloride (C[H.sub.2] = CHC[H.sub.2]Cl), the intermediate products such as dimethylamine hydrochloride ([(C[H.sub.3]).sub.2][N.sup.+][H.sub.2]Cl), allyldimethylamine (C[H.sub.2] = CHC[H.sub.2]N[(C[H.sub.3]).sub.2]) and its hydrochloride salt (C[H.sub.2] = CHC[H.sub.2][N.sup.+]H[(C[H.sub.3]).sub.2][Cl.sup.-]), and the other byproducts such as
allyl alcohol (C[H.sub.2] = CHC[H.sub.2]OH) from the hydrolyzation of allyl chloride in alkaline medium and allyl aldehyde (C[H.sub.2] = CHCHO) from oxidation of
allyl alcohol.
(2006) Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of
allyl alcohol. J.
Administration of
allyl alcohol and retrorsine leads to an elevation of GPT levels before surgery in comparison to the standard level of 48 U/L (Figure 4(f)).
In May, SDK completed the expansion of its
allyl alcohol production capacity at Oita Petrochemical Complex, raising the capacity from 56,000 tons a year to 70,000 tons a year.
First, a monomer is produced by reacting
allyl alcohol and the acid phthalic anhydride.
- Increased
allyl alcohol production from 50,000 tons to 56,000 tons/year
In this study, we looked at the effect of styrene
allyl alcohol (SAA) polyols as partial replacements for pentaerythritol (PE) and phthalic anhydride (PAN) in long-oil alkyds.
It is only after four in situ chemical transformations (oxidation to the selenoxide, [2,3]-sigmatropic rearrangement, a second oxidation and loss of
allyl alcohol) that the true catalyst (4) is generated (equation 1).
Allyl alcohol as a by-product was removed by a Dean stark trap, and the removal of diols was prevented.
We initiated the synthesis of BH derived
allyl alcohols with various aromatic aldehydes with methyl acrylate in the presence of DABCO.
Phosphotungstic acid (PTA) is efficient and eco-friendly catalyst in oxidation of organic compounds such as aromatic amines [10], aromatic alcohols [11],
allyl alcohols [12], styrene [13], oximes [14], benzhydrols [15] etc.