a statement of a chemical reaction in the form of chemical signs, chemical formulas, numbers, and mathematical signs. Although the possibility of such statements on the basis of the law of conservation of mass was suggested by A. Lavoisier in 1789, chemical equations came into general use only in the first half of the 19th century.
A chemical equation consists of a left side and a right side joined together by an equal-sign. Sometimes, the symbol → is used in place of an equal-sign in order to indicate the direction of a reaction, with double arrows (⇄) used in the case of reversible reactions. The formulas for the reactants are written on the left side, and those for the products are written on the right; + signs are placed between the formulas on each side of the equation.
In writing chemical equations, the mass of the products must be equal to that of the reactants, and the number of atoms of any given element must be the same on both sides of the equation. Coefficients, which must be whole numbers, are placed in front of the formulas for the reactants and products. For example, knowing that water and carbon dioxide are formed from the combustion of methane in oxygen, the chemical equation for this reaction may be written immediately:
(1) CH4 + 2O2 = 2H2O + CO2
In more complicated cases, other methods are used, such as those for redox reactions (seeOXIDATION-REDUCTION REACTION) and those based on the solution of systems of indeterminate equations. For example, assume that the coefficients in the chemical equation for the roasting of pyrite (FeS2) in oxygen are sought:
(2) xFeS2 + yO2= zFe2O3 + tSO2
It is obvious that x = 2z, t = 2x, and 2y = 3z + 2t. Letting z = 1, we have x = 2, t = 4, and y = 5.5. Multiplying these numbers by 2, we obtain
4FeS2 + 11O2 = 2Fe2O3 + 8SO2
Chemical equations serve as a basis for calculations required in the laboratory and in industry.
S. A. POGODIN