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cetane

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cetane

a colourless insoluble liquid alkane hydrocarbon used in the determination of the cetane number of diesel fuel. Formula: C16H34
Collins Discovery Encyclopedia, 1st edition © HarperCollins Publishers 2005

cetane

[′sē‚tān]
(organic chemistry)
n-hexadecane
McGraw-Hill Dictionary of Scientific & Technical Terms, 6E, Copyright © 2003 by The McGraw-Hill Companies, Inc.
The following article is from The Great Soviet Encyclopedia (1979). It might be outdated or ideologically biased.

Cetane

 

(also n-hexadecane), the saturated hydrocarbon CH3(CH2)14CH3. A colorless liquid, cetane has a melting point of 18.2°C, a boiling point of 286.8°C, and a density of 0.770 g/cm3 at 25°C. Insoluble in water, it is soluble in benzene, hot absolute ethanol, ether, and other organic solvents. Cetane is produced by various methods, such as heating n-octyl bromide together with sodium (seeWURTZ REACTION). Cetane is used as a standard for measuring the quality of diesel fuel (see).

The Great Soviet Encyclopedia, 3rd Edition (1970-1979). © 2010 The Gale Group, Inc. All rights reserved.
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Figure 5 shows an interesting behavior of hydro-philic samples (M) when hexadecane (nonpolar) solvent is used as a test liquid.
The petroleum diesel fuel (PDF) represented by hexadecane releases 3.1 kg of carbon dioxide per 1 kg of fuel used in combustion.
After 20-40 minutes of exposure, 96% showed hydrocarbons of longer chain lengths including tetradecane, pentadecane and hexadecane. Certain panelists exhibited ketones and residuals of cosmetic products such as linalool, dihydromethyl jasmonate, ionones, glycols, BHT and silicone.
The new fluid supersedes the previous Standard Reference Material 1490 Non-linear Fluid Standard, which was composed of a high-molecular-mass polyisobutylene dissolved in normal hexadecane. The new standard fluid SRM 2490 consists of a similar high-molecular-mass polyisobutylene dissolved in 2,6,10, 14-tetramethylpentadecane (common name pristane).
Prior studies by Landman and his colleagues found that a waxy lubricant such as hexadecane would separate into four or five stable, motion-resistant layers, but only if the size of the gap filled by the lubricant remained fixed.
A thin film of hexadecane, a hydrocarbon lubricant, was introduced into the simulation.
Category Main components Aromatic hydrocarbons Ethylbenzene, 1,3-dimethyl benzene, 1-methylene lH-indene, butylated hydroxy toluene, 1-methylnaphthalene, 2-methylnaphthalene Alkanes Undecane, dodecane, tridecane, tetradecane, pentadecane, hexadecane, 2,6,10-trimethyl dodecyl, 4-(prop-2 loxypropangl)octane, 2,6-dimethyl decane Alkenes 2-Propenylidene cyclobutene, cedrene, Seychelles alkene Aldehydes and ketones Hexanal, nonanal, benzaldehyde, acetophenone, undecanal Esters Butyl butyrate, 3-methyl heptanol acetate, 2 acrylic acid 2 ethylhexyl ester, oxalic acid acrylate Others TV-butyl ether
2), including 11 different hydrocarbons (no-nane 3.23%, decane 1.61%, limonene 9.08%, dodecane 5.44%, tetradecane 7.83%, dotriacontane 9.25%, ethylbenzene 2.70%, 1,3-dimethyl benzene 5.70%, biphenyl 7.97%, octane 1.58%, and hexadecane 11.39%), 2 alcohols (dimethyl hexadecanol 2.18% and borneol 16.02%), and 1 aldehyde (nonaldehyde 16.05%).
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