Franck, "Liquid mixture of sodium and sodium hydride at high pressures and temperatures," Physical Chemistry Chemical Physics, vol.
Mechanism of the formation of sodium hydride catalyzed by carbon monoxide," Collection of Czechoslovak Chemical Communications, vol.
The compound 3 (0.1 mmol) was dissolved in DMF (10.0 mL) followed by the addition of sodium hydride (0.1 mmol) in a 50 mL round bottom flask.
The synthesized compound, N(1,3 Benzodioxol5yl)N(4bromobenzyl)4 methylbenzene sulfonamide (5i) was produced by stirring 3 with 4bromobenzyl bromide (4i) for 34 hours in DMF as polar aprotic solvent and sodium hydride as weak base.
The
sodium hydride removes the acidic hydrogen attached to nitrogen of sulfamyl group and alkyl/aralkyl groups are attached.
Before the polymerization reaction,
sodium hydride was reacted with melting lauryllactam.
The sodium salt of propyl p-hydroxybenzoate was prepared by the slow addition of propyl p-hydroxy-benzoate (77.7 g, 0.43 mol) in THF (500 ml) to a suspension of
sodium hydride (13.8 g, 600/a dispersion) in THF (800 ml).
Sodium phenoxide was prepared from the reaction of phenol (1.7 g, 17 mmol) and
sodium hydride (0.7 g, 17 mmol) in 50 mL of THF.