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Stannite

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stannite

[′sta‚nīt]
(mineralogy)
Cu2FeSnS4 A steel-gray or iron-black mineral crystallizing in the tetragonal system and occurring in granular masses; luster is metallic, hardness is 4 on Mohs scale, and specific gravity is 4.3-4.53. Also known as bell-metal ore; tin pyrites.
McGraw-Hill Dictionary of Scientific & Technical Terms, 6E, Copyright © 2003 by The McGraw-Hill Companies, Inc.
The following article is from The Great Soviet Encyclopedia (1979). It might be outdated or ideologically biased.

Stannite

 

a mineral of the sulfide class, with the chemical composition Cu2FeSnS4. Stannite contains 29.58 percent Cu, 12.99 percent Fe, 27.5 percent Sn, and 29.8 percent S, as well as admixtures of Zn, Sb, Cd, Pb, and Ag. High-temperature stannite, which occurs in pegmatites, quartz-feldspar veins, and greisens, has isometric symmetry; low-temperature stannite, a widespread mineral of cassiterite-sulfide deposits, has tetragonal symmetry and a crystal structure similar to that of chalcopyrite.

Stannite occurs as fringes around grains of cassiterite and chalcopyrite, as solid granular masses, and as faceted grains of pseu-dotetrahedral and more intricate shapes. The mineral has a steel-gray color with an olive-green tint. Its hardness on Mohs’ scale is 3–4.5, and its density is 4,300–4,500 kg/m3. Stannite is brittle and a good conductor of electricity. It is formed in hydrothermal deposits and, less frequently, in pegmatites and greisens in association with wolframite, chalcopyrite, cassiterite, sphalerite, gray copper ore, and pyrrhotite.

The largest known accumulations of stannite in the USSR are in Primor’e Krai (Dal’negorsk deposit), the Northeast (Kheta), and Central Tadzhikistan (Mushiston). Abroad, there are large deposits in Bolivia (Potosí, Atocha). In sufficient concentrations, stannite may be used as a tin ore.

A. B. PAVLOVSKII

The Great Soviet Encyclopedia, 3rd Edition (1970-1979). © 2010 The Gale Group, Inc. All rights reserved.
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References in periodicals archive
In 1960, Pamplin had proposed stannite ([Cu.sub.2]FeSn[S.sub.4]) quaternary compound semiconductor structures [8] of ultra-crystal pack in Nature.
[Cu.sub.2]ZnSn[S.sub.4] can be divided into two structures, stannite and kesterite, according to the different locations of Cu and Zn, as shown in Figure 2.
found that the monocrystal [Cu.sub.2]ZnSn[Se.sub.4] was of the stannite structure [16].
There are still some differences between stannite and kesterite, but there is no unified conclusion till today.
Haeuseler, "Far infrared studies on stannite and wurtzstannite type compounds," Spectrochimica Acta A: Molecular Spectroscopy, vol.
Over the ensuing years, these specimens have been followed by more than 30 "best of species," including orange scheelite crystals to 20 cm, lustrous black cassiterite crystals to 15 cm, ferberite, arsenopyrite, fluorite of all colors, pyromorphite, mimetite, and rarities such as kermesite, helvite, stannite, kesterite and even common minerals such as calcite and quartz.
The sulfides and Sulfosalts are very well represented, most notably arsenopyrite, bismuthinite, bournonite, cylindrite, franckeite, pyrargyrite, pyrite, stannite, stibnite, teallite, and wurtzite Among the oxides, cassiterite and quartz are most important and siderite is the most important carbonate.
Next, consider Brian's excellent specimens of the familiar sulfosalt species from the San Jose mine, Oruro Department: unusually lustrous black franckeite in intergrown shaggy spherical aggregates to 7 cm; four fine thumbnails of andorite in thin, metallic gray dull-lustered loose aggregate s; and perhaps 50 specimens of stannite crystals in those tight little spheres we have seen before, but these overlaid heavily by unusually brilliant zinkenite needles.
Stannite has been identified as an accessory mineral in the sulfide suite at the Nikolaevskiy mine.
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