Lu, Highly Efficient N-formylation of Amines with Ammonium Formate
Catalyzed by Nano-Fe3O4 in PEG-400, RSC Adv.
9 [micro]m), P/N 25502-102130 Mobile Phase A1: 20mM Ammonium formate
in water, pH 3, (P/N Ammonium formate
A114-50) A2: 20 mM Ammonium formate
in water, pH 4 A3: 20 mM Ammonium acetate in water, pH 5, (P/N Ammonium acetate A115-50) A4: 20 mM Ammonium acetate in water, pH 5.
Formic acid, ammonium formate
, and ammonium phosphate were obtained from Sigma Aldrich; LC-MS-grade methanol and acetonitrile from Burdick & Jackson; Strata-X-CW weak cation exchange (WCX) solid-phase extraction (SPE) cartridges (3 mL) from Phenomenex; and Oasis WCX [mu]Elution 96-well SPE plates from Waters.
Eluent A was water and eluent B was acetonitrile--water (95:5), both containing 2 mM ammonium formate
and 50 mM formic acid (Quilliam 2003).
Ten ppb spiked river samples are simply filtered, 10 mM of ammonium formate
is added and then pipetted onto a mesh.
Denoxium is a solution of ammonium formate
and urea and it has a freezing point of -30oC.
(LC-MS grade) was purchased from Sigma-Aldrich Chemie GmbH.
Volatile salts, ammonium acetate and ammonium formate
are used in LCMS applications to improve ionization under neutral conditions in ESI/MS, while acetic acid enhances chromatography separation under acidic conditions.
The enzyme activities for GAA, GLA, and IDUA were compared in sodium formate and ammonium formate
buffers at pH 4.
We obtained acetonitrile and methanol from Carlo Erba, dichloromethane and isopropanol from Prolabo, and formic acid and ammonium formate
To each well we added 70 /,L of 5 mmol/L ammonium formate
in methanol-chloroform (3:1 by volume), and the sample was infused into the mass spectrometer.