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Related to Austenite: pearlite, cementite
one of the structural components of iron-carbon alloys, a solid solution of carbon (to 2 percent) and alloying elements in gamma iron. Austenite derives its name from the English scientist W. Roberts-Austen (1843–1902). The crystal lattice is a cube with centered facets. Austenite is nonmagnetic. Its density exceeds that of other structural components of steel. In carbon steels and cast irons, austenite resists temperatures exceeding 723° C. In the process of cooling steel, austenite is transformed into other structural components. In iron-carbon alloys containing nickel, manganese, and chromium in significant amounts, austenite can be completely preserved after cooling to room temperature (for example, stainless chromium-nickel steels). Depending on the composition of the steel and its relative cooling, austenite can be partially preserved in carbon or alloyed steels (so-called retained austenite).
The study of the transformations of austenite began with the discoveries of D. K. Chernov (1868). He first pointed out the connection between these transformations and the critical points of steel. During cooling below these points, phases are formed with different mutual arrangements of atoms in the crystal lattice and in some cases with a modification of chemical composition.
Three areas of austenite transformation have been identified. In the upper temperature regions (723°-550°C) austenite disintegrates to form pearlite, a eutectoid mixture composed of alternating layers of ferrite (carbon concentration by weight, 0.02 percent) and cementite (carbon concentration by weight, 6.7 percent). Pearlite transformation begins after some heating, and after sufficient time the austenite disintegrates completely. Below a particular temperature (Ml), which depends on the content of carbon (for steel with 0.8 percent carbon it is about 240° C), a martensite transformation of austenite occurs. This transformation consists of a regular rearrangement of the crystal lattice, during which atoms do not trade places. In the interval between 550° C and Ml, an intermediate (bainite) transformation of austenite occurs. This transformation, like that of pearlite, begins after an incubation period and can be suppressed by quick cooling; like the martensite transformation, it can be stopped by constant temperature (a certain amount of austenite remains untransformed) and is accompanied by the formation of a characteristic relief on the surface of a section. During intermediate transformation, the ordered displacements of metallic atoms are coupled with the diffusional redistribution of carbon atoms into austenite. As a result, a ferrito-cementite mixture—and frequently a retained austenite with a carbon content that differs from the average—is formed. During intermediate transformation, cementite can separate itself directly from austenite or from a ferrite saturated with carbon.
When austenite alloys containing more than 2 percent carbon are converted in the presence of primary formations of cementite or graphite, the resulting structures are unique.
The diagram, which shows the proportion of transformed austenite on temperature-time coordinates, gives a representation of the kinematics of the transformation of austenite. On the diagram of alloyed austenite the transformation regions of pearlite (640°-520° C) and intermediate transformations (480°-300° C) are clearly delineated, and there is a temperature zone of high durability of austenite (see Figure 1). In pearlite transformation of alloyed austenite, a mixture of ferrite and special carbides occurs in many cases.
Alloying elements, with the exception of cobalt, increase the duration of the incubation period of the pearlite transformation.
The laws of austenite transformation are utilized in the treatment of alloyed steels for various purposes of thermal and thermomechanical treatment. The diagrams of austenite transformations permit the establishment of methods of annealing steel, cooling items, isothermic hardening, and so on.
REFERENCESKurdiumov, G. V. lavleniia zakalki i otpuska stali. Moscow, 1960.
Entin, R. I. Prevrashcheniia austenita V stali. Moscow, 1960.