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configuration interaction |
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configuration interaction [kən‚fig·yə′rā·shən in·tər′ak·shən] (physical chemistry) Interaction between two different possible arrangements of the electrons in an atom (or molecule); the resulting electron distribution, energy levels, and transitions differ from what would occur in the absence of the interaction. How to thank TFD for its existence? Tell a friend about us, add a link to this page, add the site to iGoogle, or visit webmaster's page for free fun content. |
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[1] Effects of Configuration Interaction on Intensities and Phase Shifts, U. 12] raised to the first power combined with a conventional nonorthogonal configuration interaction basis. |
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