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diastereomer |
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No references found | The enantiomeric fractions (EFs) reported here are corrected using the responses of the isotopically labeled diastereomer standards as described elsewhere (Marvin et al. Other subjects covered include synthesis and electronic properties of assemblies of diastereomers of nickel II complexes with tetracyanometalates, synthesis of functionalized pyrazoles, stereochemical aspects of interaction between some monosaccharides and l-alpha-amino acids in aqueous solutions, and challenges in carbohydrate chemistry. Moreover, during the oxidative work-up procedure in basic conditions the lactone ring may open and, together with the following relactonization, there is a risk of racemization of (1S, 5R, 6R)4a (the enantiopurity of the other diastereomer (1S, 5R, 6S)-4a is not affected). |
diastereomer |
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