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double-bond shift

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double-bond shift [¦dəb·əl ¦bänd ′shift]
(organic chemistry)
In an organic molecular structure, the occurrence when a pair of valence bonds that join a pair of carbons (or other atoms) shifts, via chemical reaction, to a new position, for example, H2C=C‒C‒CH2(butene-1) to H2C‒C=C‒CH2(butene-2).


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