electricity

electricity, class of phenomena arising from the existence of charge. The basic unit of charge is that on the proton or electron—the proton's charge is designated as positive while the electron's is negative. There are three basic systems of units used to measure electrical quantities, the most common being the one in which the ampere is the unit of current, the coulomb is the unit of charge, the volt is the unit of electromotive force, and the ohm is the unit of resistance, reactance, or impedance (see electric and magnetic units).

Properties of Electric Charges

According to modern theory, most elementary particles

Basic Constituents of Matter

Molecules are built up from the atom , which is the basic unit of any chemical element .
.....  of matter possess charge, either positive or negative. Two particles with like charges, both positive or both negative, repel each other, while two particles with unlike charges are attracted (see Coulomb's law). The electric force between two charged particles is much greater than the gravitational force between the particles. The negatively charged electrons in an atom are held near the nucleus because of their attraction for the positively charged protons in the nucleus.

If the numbers of electrons and protons are equal, the atom is electrically neutral; if there is an excess of electrons, it is a negative ion

Positive and Negative Electric Charges

A neutral atom or group of atoms becomes an ion by gaining or losing one or more electrons or protons.
..... ; and if there is a deficiency of electrons, it is a positive ion. Under various circumstances, the number of electrons associated with a given atom may change; chemical bonding results from such changes, with electrons being shared by more than one atom in covalent bonds or being transferred from one atom to another in ionic bonds (see chemical bond). Thus many of the bulk properties of matter ultimately are due to the electric forces among the particles of which the substance is composed. Materials differ in their ability to allow charge to flow through them (see conduction; insulation); materials that allow charge to pass easily are called conductors, while those that do not are called insulators, or dielectrics. A third class of materials, called semiconductors, conduct charge under some conditions but not under others.

Properties of Charges at Rest

Electrostatics is the study of charges, or charged bodies, at rest. When positive or negative charge builds up in fixed positions on objects, certain phenomena can be observed that are collectively referred to as static electricity. The charge can be built up by rubbing certain objects together, such as silk and glass or rubber and fur; the friction between the objects causes electrons to be transferred from one to the other—from a glass rod to a silk cloth or from fur to a rubber rod—with the result that the object that has lost the electrons has a positive charge and the object that has gained them has an equal negative charge. An electrically neutral object can be charged by bringing it in contact with a charged object: if the charged object is positive, the neutral object gains a positive charge when some of its electrons are attracted onto the positive object; if the charged object is negative, the neutral object gains a negative charge when some electrons are attracted onto it from the negative object.

A neutral conductor may be charged by induction using the following procedure. A charged object is placed near but not in contact with the conductor. If the object is positively charged, electrons in the conductor are drawn to the side of the conductor near the object. If the object is negatively charged, electrons are drawn to the side of the conductor away from the object. If the conductor is then connected to a reservoir of electrons, such as the ground, electrons will flow onto or off of the conductor with the result that it acquires a charge opposite to that of the charged object brought near it.

See also pole, in electricity and magnetism.

Properties of Charges in Motion

Electrodynamics is the study of charges in motion. A flow of electric charge constitutes an electric current. Historically, the direction of current was described in terms of the motion of imaginary positive charges; this convention is still used by many scientists, although it is directly opposite to the direction of electron flow, which is now known to be the basis of electric current in solids. Current considered to be composed of imaginary positive charges is often called conventional current. In order for a current to exist in a conductor, there must be an electromotive force (emf), or potential difference, between the conductor's ends. An electric cell, a battery of cells, and a generator are all sources of electromotive force; any such source with an external conductor connected from one of the source's two terminals to the other constitutes an electric circuit. If the source is a battery, the current is in one direction only and is called direct current (DC). If the source is a generator without a commutator, the current direction reverses twice during each rotation of the armature, passing first in one direction and then in the other; such current is called alternating current (AC). The number of times alternating current makes a double reversal of direction each second is called the frequency of the current; the frequency of ordinary household current in the U.S. is 60 cycles per sec (60 Hz), and electric devices must be designed to operate at this frequency.

In a solid the current consists not of a few electrons moving rapidly but of many electrons moving slowly; although this drift of electrons is slow, the impulse that causes it when the circuit is completed moves through the circuit at nearly the speed of light. The movement of electrons in a current is not steady; each electron moves in a series of stops and starts. In a direct current, the electrons are spread evenly through the conductor; in an alternating current, the electrons tend to congregate along the surface of the conductor. In liquids and gases, the current carriers are not only electrons but also positive and negative ions.

History of Electricity

From the writings of Thales of Miletus it appears that Westerners knew as long ago as 600 B.C. that amber becomes charged by rubbing. There was little real progress until the English scientist William Gilbert in 1600 described the electrification of many substances and coined the term electricity from the Greek word for amber. As a result, Gilbert is called the father of modern electricity. In 1660 Otto von Guericke invented a crude machine for producing static electricity. It was a ball of sulfur, rotated by a crank with one hand and rubbed with the other. Successors, such as Francis Hauksbee, made improvements that provided experimenters with a ready source of static electricity. Today's highly developed descendant of these early machines is the Van de Graaf generator, which is sometimes used as a particle accelerator. Robert Boyle realized that attraction and repulsion were mutual and that electric force was transmitted through a vacuum (c.1675). Stephen Gray distinguished between conductors and nonconductors (1729). C. F. Du Fay recognized two kinds of electricity, which Benjamin Franklin and Ebenezer Kinnersley of Philadelphia later named positive and negative.

The Leyden Jar and the Quantitative Era

Progress quickened after the Leyden jar was invented in 1745 by Pieter van Musschenbroek. The Leyden jar stored static electricity, which could be discharged all at once. In 1747 William Watson discharged a Leyden jar through a circuit, and comprehension of the current and circuit started a new field of experimentation. Henry Cavendish, by measuring the conductivity of materials (he compared the simultaneous shocks he received by discharging Leyden jars through the materials), and Charles A. Coulomb, by expressing mathematically the attraction of electrified bodies, began the quantitative study of electricity.

A new interest in current began with the invention of the battery. Luigi Galvani had noticed (1786) that a discharge of static electricity made a frog's leg jerk. Consequent experimentation produced what was a simple electron cell using the fluids of the leg as an electrolyte and the muscle as a circuit and indicator. Galvani thought the leg supplied electricity, but Alessandro Volta thought otherwise, and he built the voltaic pile, an early type of battery, as proof. Continuous current from batteries smoothed the way for the discovery of G. S. Ohm's law (pub. 1827), relating current, voltage (electromotive force), and resistance (see Ohm's law), and of J. P. Joule's law of electrical heating (pub. 1841). Ohm's law and the rules discovered later by G. R. Kirchhoff regarding the sum of the currents and the sum of the voltages in a circuit (see Kirchhoff's laws) are the basic means of making circuit calculations.

Era of Electromagnetism

In 1819 Hans Christian Oersted discovered that a magnetic field surrounds a current-carrying wire. Within two years André Marie Ampère had put several electromagnetic laws into mathematical form, D. F. Arago had invented the electromagnet, and Michael Faraday had devised a crude form of electric motor. Practical application of a motor had to wait 10 years, however, until Faraday (and earlier, independently, Joseph Henry) invented the electric generator with which to power the motor. A year after Faraday's laboratory approximation of the generator, Hippolyte Pixii constructed a hand-driven model. From then on engineers took over from the scientists, and a slow development followed; the first power stations were built 50 years later (see power, electric).

In 1873 James Clerk Maxwell had started a different path of development with equations that described the electromagnetic field, and he predicted the existence of electromagnetic waves traveling with the speed of light. Heinrich R. Hertz confirmed this prediction experimentally, and Marconi first made use of these waves in developing radio (1895). John Ambrose Fleming invented (1904) the diode rectifier vacuum tube as a detector for the Marconi radio. Three years later Lee De Forest made the diode into an amplifier by adding a third electrode, and electronics had begun. Theoretical understanding became more complete in 1897 with the discovery of the electron by J. J. Thomson. In 1910–11 Ernest R. Rutherford and his assistants learned the distribution of charge within the atom. Robert Millikan measured the charge on a single electron by 1913.

Bibliography

See D. L. Anderson, Discovery of the Electron: The Development of the Atomic Concept of Electricity (1964); W. T. Scott, The Physics of Electricity and Magnetism (2d ed. 1966); M. Kaufman and J. A. Wilson, Basic Electricity (1973); E. T. Whittaker, History of Theories of Aether and Electricity (1954, repr. 1987).

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electricity

Phenomenon associated with stationary or moving electric charges. The word comes from the Greek elektron (“amber”); the Greeks discovered that amber rubbed with fur attracted light objects such as feathers. Such effects due to stationary charges, or static electricity, were the first electrical phenomena to be studied. Not until the early 19th century were static electricity and electric current shown to be aspects of the same phenomenon. The discovery of the electron, which carries a charge designated as negative, showed that the various manifestations of electricity are the result of the accumulation or motion of numbers of electrons. The invention of the incandescent lightbulb (1879) and the construction of the first central power station (1881) by Thomas Alva Edison led to the rapid introduction of electric power into factories and homes. See also James Clerk Maxwell.

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electricity

The flow of electrons in a circuit. The speed of electricity is the speed of light (approximately 186,000 miles per second or 300,000,000 meters per second). In a wire, it is slowed due to the resistance in the material.

Its pressure, or force, is measured in "volts," and its flow, or current, is measured in "amperes" or simply "amps." The amount of work it produces is measured in "watts" (amps X volts).

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electricity

1. any phenomenon associated with stationary or moving electrons, ions, or other charged particles

2. the science concerned with electricity

3. an electric current or charge

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Electricity

Physical phenomena involving electric charges, their motions, and their effects. The motion of a charge is affected by its interaction with the electric field and, for a moving charge, the magnetic field. The electric field acting on a charge arises from the presence of other charges and from a time-varying magnetic field. The magnetic field acting on a moving charge arises from the motion of other charges and from a time-varying electric field. Thus electricity and magnetism are ultimately inextricably linked. In many cases, however, one aspect may dominate, and the separation is meaningful. See Electric charge, Electric field, Magnetism

The quantitative development of electricity began late in the eighteenth century. J. B. Priestley in 1767 and C. A. Coulomb in 1785 discovered independently the inverse-square law for stationary charges. This law serves as a foundation for electrostatics. See Coulomb's law, Electrostatics

In 1800 A. Volta constructed and experimented with the voltaic pile, the predecessor of modern batteries. It provided the first continuous source of electricity. In 1820 H. C. Oersted demonstrated magnetic effects arising from electric currents. The production of induced electric currents by changing magnetic fields was demonstrated by M. Faraday in 1831. In 1851 he also proposed giving physical reality to the concept of lines of force. This was the first step in the direction of shifting the emphasis away from the charges and onto the associated fields. See Electromagnetic induction, Electromagnetism, Lines of force

In 1865 J. C. Maxwell presented his mathematical theory of the electromagnetic field. This theory, which proposed a continuous electric fluid, not only synthesized a unified theory of electricity and magnetism, but also showed optics to be a branch of electromagnetism. See Electromagnetic radiation, Maxwell's equations

The developments of theories about electricity subsequent to Maxwell have all been concerned with the microscopic realm. Faraday's experiments on electrolysis in 1833 had indicated a natural unit of electric charge, thus pointing toward a discrete rather than continuous charge. The existence of electrons, negatively charged particles, was postulated by A. Lorenz in 1895 and demonstrated by J. J. Thomson in 1897. The existence of positively charged particles (protons) was shown shortly afterward (1898) by W. Wien. Since that time, many particles have been found having charges numerically equal to that of the electron. The question of the fundamental nature of these particles remains unsolved, but the concept of a single elementary charge unit is apparently still valid. See Baryon, Electron, Elementary particle, Hyperon, Meson, Proton, Quarks

The sources of electricity in modern technology depend strongly on the application for which they are intended.

The principal use of static electricity today is in the production of high electric fields. Such fields are used in industry for testing the ability of components such as insulators and condensers to withstand high voltages, and as accelerating fields for charged-particle accelerators. The principal source of such fields today is the Van de Graaff generator. See Particle accelerator

The major use of electricity arises in devices using direct current and low-frequency alternating current. The use of alternating current, introduced by S. Z. de Ferranti in 1885–1890, allows power transmission over long distances at very high voltages with a resulting low-percentage power loss followed by highly efficient conversion to lower voltages for the consumer through the use of transformers. See Electric current

Large amounts of direct current are used in the electrodeposition of metals, both in plating and in metal production, for example, in the reduction of aluminum ore.

The principal sources of low-frequency electricity are generators based on the motion of a conducting medium through a magnetic field. The moving charges interact with the magnetic field to give a charge motion that is normal to both the direction of motion and the magnetic field. In the most common form, conducting wire coils rotate in an applied magnetic field. The rotational power is derived from a water-driven turbine in the case of hydroelectric generation, or from a gas-driven turbine or reciprocating engine in other cases.

Many high-frequency devices, such as communications equipment, television, and radar, involve the consumption of only moderate amounts of power, generally derived from low-frequency sources. If the power requirements are moderate and portability is needed, the use of ordinary chemical batteries is possible. Ion-permeable membrane batteries are a later development in this line. Fuel cells, particularly hydrogen-oxygen systems, are being developed. They have already found extensive application in earth satellite and other space systems. The successful use of thermoelectric generators based on the Seebeck effect in semiconductors has been reported. See Thermoelectricity

The solar battery, also a semiconductor device, has been used to provide charging current for storage batteries in telephone service and in communications equipment in artificial satellites.

Direct conversion of mechanical energy into electrical energy is possible by utilizing the phenomena of piezoelectricity and magnetostriction. These have some application in acoustics and stress measurements. Pyroelectricity is a thermodynamic corollary of piezoelectricity. See Magnetostriction, Piezoelectricity, Pyroelectricity