exterior complex scaling

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exterior complex scaling [ik¦stir·ē·ər ¦käm‚pleks ‚skāl·iŋ]

(atomic physics)

A mathematical transformation, which has been used to simplify the boundary conditions on the wave functions in an electron-atom collision, in which the variabler, representing the distance of the electron from the nucleus, is replaced, at values ofrgreater than some constantR, byR+ (r-R)C, whereCis a complex number with unit modulus and positive imaginary part.

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