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goethite

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goethite

Widespread iron hydroxide mineral, α-FeO(OH), the most common ingredient of iron rust. In terms of relative abundance, it is second only to hematite (α-Fe2O3) among iron oxides. Goethite varies in colour from yellow-brown to red and is the source for the pigment known as yellow ocher; it is also the primary mineral in some important iron ores, such as those in the Alsace-Lorraine basin in France. Other important deposits are found in the southern Appalachian Mountains of the U.S., and in Brazil, South Africa, Russia, and Australia.


goethite [′gə‚tīt]
(mineralogy)
FeO(OH) A yellow, red, or dark-brown mineral crystallizing in the orthorhombic system, although it is usually found in radiating fibrous aggregates; a common constituent of natural rust or limonite. Also known as xanthosiderite.


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Increasing the pH would facilitate ferrous and ferric ion oxidation to goethite (FeOOH), which is water insoluble and thus not bioavailable for redox reactions (Lowson 1982; Singer and Stumm 1969).
Goethite formation requires water, and the mineral, when heated, can slowly convert to hematite.
381), but also in caves on dripstone and flowstone speleothems composed of calcite, epsomite, goethite, and even mud.
 
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