hydrogenolysis


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hydrogenolysis

[′hī·drə·jə′näl·ə·səs]
(chemistry)
A reaction in which hydrogen gas causes a chemical change that is similar to the role of water in hydrolysis.
References in periodicals archive ?
Protecting-group free glycosylation by using 3,5-dibenzyloxytriazinyl glycosides as glycosyl donors under hydrogenolysis conditions.
In all cases, glycerol is converted to propylene glycol via hydrogenolysis.
New homogeneous ionic hydrogenation and hydrogenolysis catalysts could offer a pathway for the efficient transformation of renewable naturally abundant sugar poly alcohols to polymer building blocks.
Catalytic effects of iron compounds and the role of sulfur in coal-liquefaction and hydrogenolysis of SCR // Fuel Process Technol.
Yet many other methods exist, including hydrogenolysis, rateometric colorimetry, energy dispersive XRF (EDXRF) and pulsed flame photometric detector (PFPD).
In addition, the potential of catalysis making use of self-heated and magnetically recoverable NPs will be studied in solution (reduction of arenes or oxygenated functions, hydrogenation and hydrogenolysis of biomass platform molecules, Fischer-Tropsch).
Summary: Hydrogenolysis of biomass-derived glycerol is an alternative route to produce 1, 2-propanediol.
Somorjai; The dehydrogenation and hydrogenolysis of cyclohexane and cyclohexene on stepped (high miller index) platinum surfaces; J.
Some of the beta-lactams so obtained were subjected to hydrogenolysis with ammonium formate and Pd/C catalyst.
The selected model reactions are situated in the area of biomass upgrading to fuels and chemicals: fast pyrolysis oil stabilization, glycerol hydrogenolysis and selective oxidation of (bio)ethanol to acetaldehyde.