hydrosilylation

hydrosilylation

[¦hī·drō‚sil·ē′ā·shən]
(organic chemistry)
The addition of a Si-H bond to a C-C double bond of an olefin.
References in periodicals archive ?
8]) as a multifunctional POSS molecule is usually used to prepare star-shaped or network hybrid polymers by hydrosilylation reaction.
We have successfully applied the hydrosilylation of polar groups comprising silanes to SSBRs.
To synthesize the fluoroalkyl silicone materials used herein, several silicone backbones were modified with fluoroalkyl alone; fluoroalkyl and polyether; or fluoroalkyl and alkyl using well known hydrosilylation procedures.
Aminosilanes are synthesized catalytically (different Rh-complexes and Speier's catalyst [9]) by hydrosilylation of an appropriate aminoalkene with compatible alkoxysilane [10-12].
First, octasilane POSS was functionalized with dimethylamino groups by hydrosilylation with allyl-dimethylamine.
Catalysts for the 100% atom-efficient hydrosilylation, -phophination and -amination of unsaturated substrates will be prepared
PDMS with either vinyl or hexenyl groups is crosslinked with hydride-functional PDMS chains via a hydrosilylation or addition reaction.
This confirmed that the hydrosilylation between carbosiloxane II and AGE was almost complete.
The terminal vinyl group in the epoxy ester can react with PMHS by hydrosilylation in the presence of suitable catalyst under heat (23-25).
The polymerization processes that have been successfully utilized with this parallel polymerization system include free radical polymerization, ring-opening polymerization, atom-transfer-radical-polymerization, urethane-silox-ane block copolymerization, (50), (51) and siloxane functionalization via hydrosilylation.
Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis
The compatibilizers were synthesized through hydrosilylation reactions (17-19).