8]) as a multifunctional POSS molecule is usually used to prepare star-shaped or network hybrid polymers by hydrosilylation
We have successfully applied the hydrosilylation
of polar groups comprising silanes to SSBRs.
To synthesize the fluoroalkyl silicone materials used herein, several silicone backbones were modified with fluoroalkyl alone; fluoroalkyl and polyether; or fluoroalkyl and alkyl using well known hydrosilylation
Aminosilanes are synthesized catalytically (different Rh-complexes and Speier's catalyst ) by hydrosilylation
of an appropriate aminoalkene with compatible alkoxysilane [10-12].
First, octasilane POSS was functionalized with dimethylamino groups by hydrosilylation
Catalysts for the 100% atom-efficient hydrosilylation
, -phophination and -amination of unsaturated substrates will be prepared
PDMS with either vinyl or hexenyl groups is crosslinked with hydride-functional PDMS chains via a hydrosilylation
or addition reaction.
This confirmed that the hydrosilylation
between carbosiloxane II and AGE was almost complete.
The terminal vinyl group in the epoxy ester can react with PMHS by hydrosilylation
in the presence of suitable catalyst under heat (23-25).
The polymerization processes that have been successfully utilized with this parallel polymerization system include free radical polymerization, ring-opening polymerization, atom-transfer-radical-polymerization, urethane-silox-ane block copolymerization, (50), (51) and siloxane functionalization via hydrosilylation
Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation
The compatibilizers were synthesized through hydrosilylation