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molecular diameter

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molecular diameter [mə′lek·yə·lər dī′am·əd·ər]
(physical chemistry)
The diameter of a molecule, assuming it to be spherical; has a numerical value of 10-8centimeter multiplied by a factor dependent on the compound or element.


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25 Correlation for Diffusion Coefficients Michaels (31) found a relationship between the reduced diffusion constant and the reduced molecular diameter for amorphous polyethylene: ln(D/[d.
How do molecules of such a liquid shift and roll when they are wedged between moving surfaces only a few molecular diameters apart?
Subsequently, it was shown that diffusivities for gases and vapors in glassy PS and PMMA, in addition to PVC, are strong exponential functions of molecular diameter (5).
 
 
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