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photoinitiated polymerization

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photoinitiated polymerization [‚fōd·ō·ə¦nish·ē‚ād·əd pə‚lim·ə·rə′zā·shən]
(physical chemistry)
A chain reaction of monomer to polymer initiated by a photogenerated radical or ion.
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In many photoinitiated polymerizations, the initiation rate is spatially inhomogeneous and there exists a gradient in polymerization rates (5-7) because the photoinitiator absorbs the radiation and so attenuates, the light intensity as a function of depth along the optical path.
Impact of radiation attenuation and temperature evolution on monomer ... by Mucci, Veronica; Cook, Wayne D.; Vallo, Claudia / Polymer Engineering and Science
A Mechanistic Photopolymerization of an Acrylate Monomer, Photoinitiated Polymerization, Vol.
Photoinitiation of multifunctional acrylates via ferrocene alkyl ... by Anderson, Julic A.; Hardgrove, Evan; Cavitt, T.Brian; Reeves, Perry C. / JCT Research
Following In Situ Photoinitiated Polymerization of Multifunctional Acrylic Monomers by Fluorescence and Photocalorimetry Simultaneously," Polymer, 43, 5355 (2002).
Process control in UV curing: in-line monitoring of the acrylate ... by Lucht, Hartmut / JCT CoatingsTech
 
 
 
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