physical chemistry, branch of science science [Lat. scientia=knowledge]. For many the term science refers to the organized body of knowledge concerning the physical world, both animate and inanimate, but a proper definition would also have to include the attitudes and methods through which
..... Click the link for more information. that combines the principles and methods of physics and chemistry. It provides a fundamental theoretical and experimental basis for all of chemistry, including organic, inorganic, and analytical chemistry. In addition, it is the foundation of chemical engineering. Topics of interest are chemical equilibrium, reaction rates, solutions, molecular weights, molecular structure, and the properties of gases, liquids, crystals, and colloids. Among other factors, the influence of temperature, pressure, electricity, light, concentration, and turbulence are considered. There are three principal approaches in physical chemistry: thermodynamics Carnot cycle after the French physicist Sadi Carnot , who first discussed the implications of such cycles. During the Carnot cycle occurring in the operation of a heat engine, a definite quantity of heat is absorbed from a reservoir at high temperature; part of this heat is
..... Click the link for more information. , involving large numbers of molecules in equilibrium; kinetics, involving chemical changes with time; and molecular structure, involving the electronic and atomic arrangements that follow from the quantum theory quantum theory, modern physical theory concerned with the emission and absorption of energy by matter and with the motion of material particles; the quantum theory and the theory of relativity together form the theoretical basis of modern physics.
..... Click the link for more information. . The latter approach is primarily theoretical and provides an understanding of the chemical bonds chemical bond, mechanism whereby atoms combine to form molecules . There is a chemical bond between two atoms or groups of atoms when the forces acting between them are strong enough to lead to the formation of an aggregate with sufficient stability to be regarded as
..... Click the link for more information. which are responsible for the structure of all materials.

Bibliography

See I. N. Levine, Physical Chemistry (4th ed. 1995); G. M. Barrow, Physical Chemistry (6th ed. 1996); P. W. Atkins, Physical Chemistry (6th ed. 1997); D. A. McQuarrie and J. D. Simon, Physical Chemistry: A Molecular Approach (1997).

physical chemistry

Branch of chemistry concerned with interactions and transformations of materials. Unlike other branches, it deals with the principles of physics underlying all chemical interactions (e.g., gas laws), seeking to measure, correlate, and explain the quantitative aspects of reactions. Quantum mechanics has clarified much for physical chemistry by modeling the smallest particles ordinarily dealt with in the field, atoms and molecules, enabling theoretical chemists to use computers and sophisticated mathematical techniques to understand the chemical behaviour of matter. Chemical thermodynamics deals with the relationship between heat and other forms of chemical energy, kinetics with chemical reaction rates. Subdisciplines of physical chemistry include electrochemistry, photochemistry (see photochemical reaction), surface chemistry, and catalysis.

physical chemistry [′fiz·ə·kəl ′kem·ə·strē]

(chemistry)

The branch of chemistry that deals with the interpretation of chemical phenomena and properties in terms of the underlying physical processes, and with the development of techniques for their investigation.

physical chemistry (redirected from physicochemical)

Bibliography

physical chemistry

physical chemistry
(redirected from physicochemical)