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Related to Radiolysis: Pulse radiolysis


(physical chemistry)
The dissociation of molecules by radiation; for example, a small amount of water in a reactor core dissociates into hydrogen and oxygen during operation.



the chemical transformations of a substance that occur upon exposure to ionizing radiation. These transformations generally involve the decomposition of the substance into simpler substances. For example, water decomposes into oxygen and hydrogen. The decomposition may be accompanied by other chemical or physical changes in the substance.

References in periodicals archive ?
The distribution of hydrogen between the vapour and liquid phases and the influence on the distribution of chemistry control agents such as boron and lithium (the latter for pH control) are of interest, since the radiolysis may be significantly affected.
Variability of the electrical state of such an amphoteric colloidal particle in water is great due to the generation, as a result of the radiolysis of water: of radicals, hydrated protons and electrons, etc.
Most of the secondary events in the [gamma] radiolysis is very much similar to the processes initiated by high energy electrons.
Oxidation of free amino acids and amino acid residues in proteins by radiolysis and by metal-catalyzed reactions.
These are followed by Appendices covering the effects of radiolysis on certain major components of food and the detection of prior radiation.
Charge Transport along Isolated Conjugated Molecular Wires Measured by Pulse Radiolysis Time-Resolved Microwave Conductivity (Ferdinand C.
The decoloration of DCP started first in the beginning of reaction, followed by the transformation of TBPB to its acidic form as a result of the delivery of HCl from the radiolysis of chloral hydrate.
Radiation induced radiolysis of water in the aqueous media of the cells which leads to production of hydroxyl radicals (*OH) that interact with the polyunsaturated fatty acids in the lipid portion of biological membranes initiating the lipid peroxidation and finally damaged the cell membranes (Azab et al.
Through radiolysis of water, it can also act indirectly by generating reactive chemical species that may damage nucleic acids, proteins, and lipids [1].
On irradiation in aqueous solution, a PEO macroradical is much more likely to be formed by reaction with hydroxyl radical, one of the products of water radiolysis (28).
This is an indication of oxidation of lipids by the irradiation process by producing OH radicals formed due mainly to water radiolysis (Lee et al.