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second-order transition

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second-order transition [′sek·ənd ¦ȯr·dər tran′zish·ən]
(thermodynamics)
A change of state through which the free energy of a substance and its first derivatives are continuous functions of temperature and pressure, or other corresponding variables.


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Although the glass transition temperature is a second-order transition which is kinetically controlled and depends on the experiment time-scale [13], its relationship to other material properties is well established.
In a second-order transition, such as the demagnetization of iron when heated, the change is continuous, exhibiting a gradual change in behavior rather than a sharp break.
A second-order transition (such as the glass transition) is manifest as a discontinuity in the DSC trace.
 
 
 
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