transition element

transition element

Any chemical element with valence electrons in two shells instead of only one. This structure gives them their outstanding ability to form ions containing more than one atom (complex ions, or coordination compounds), with a central atom or ion (often of a transition metal) surrounded by ligands in a regular arrangement. Theories on the bonding in these ions are still being refined. The elements in the periodic table from scandium to copper (atomic numbers 21–29), yttrium to silver (39–47), and lanthanum to gold (57–79, including the lanthanide series) are frequently designated the three main transition series. (Those in the actinide series and beyond, 89–111, also qualify.) All are metals, many of major economic or industrial importance (e.g., iron, gold, nickel, titanium). Most are dense, hard, and brittle, conduct heat and electricity well, have high melting points, and form alloys with each other and other metals. Their electronic structure lets them form compounds at various valences. Many of these compounds are coloured and paramagnetic (see paramagnetism) and (as do the metals themselves) often act as catalysts. See also rare earth metal.

---

transition element, metal

Chem any element belonging to one of three series of elements with atomic numbers between 21 and 30, 39 and 48, and 57 and 80. They have an incomplete penultimate electron shell and tend to exhibit more than one valency and to form complexes

---

transition element [tran′zish·ən ‚el·ə·mənt]

(chemistry)

One of a group of metallic elements in which the members have the filling of the outermost shell to 8 electrons interrupted to bring the penultimate shell from 8 to 18 or 32 electrons; includes elements 21 through 29 (scandium through copper), 39 through 47 (yttrium through silver), 57 through 79 (lanthanum through gold), and all known elements from 89 (actinium) on. Also known as transition metal.

(electromagnetism)

An element used to couple one type of transmission system to another, as for coupling a coaxial line to a waveguide.