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valence-bond method

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valence-bond method [′vā·ləns ¦bänd ‚meth·əd]
(physical chemistry)
A method of calculating binding energies and other parameters of molecules by taking linear combinations of electronic wave functions, some of which represent covalent structures, others ionic structures; the coefficients in the linear combination are calculated by the variational method. Also known as valence-bond resonance method.


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