The significant superior binding of [C.sub.2] and [C.sub.4] compared to other complexes is possibly owing to the 1,10-phenanthroline
ring analogue as coligand in the respective complexes, which favours the interaction with the DNA through [pi] - [[pi].sup.*] interaction and H-bonding .
The compounds (1-4) were reacted with the nitrogen and phosphorous donor ligands like triphenylphosphine, pyridine, 2,27 -bipyridine, and 1,10-phenanthroline
in dichloromethane in appropriate stoichiometries.
Varmuzova, "Potentiometric ion-pair titrations of metal ions forming complexes with 1,10-phenanthroline
and its derivatives," Electroanalysis, vol.
Cluster 1 contains iodochlorohydroxyquinoline, 8-hydroxyquinoline, 1,10-phenanthroline
monohydrate, and quinoline (Figure 2).
The CCm-Tf-degrading activity in the samples from IPF patients was not altered by incubation on the CCm-Tf film coated with a mixture of aprotinin and elastinal (serine proteinase inhibitors) (Figure 5, B), but it was completely abolished in the film coated with a mixture of the serine proteinase inhibitors and 1,10-phenanthroline
(a metalloproteinase inhibitor) (Figure 5, C).
Triorganotin(IV) derivatives of umbelliferone (7-hydroxycoumarin) and their adducts with 1,10-phenanthroline
:synthesis, structural and biological studies.
PAN indicator: is a mixture of sulfuric acid solution, ammonium sulfate, 1,10-phenanthroline
solution (20%), L-ascorbic acid solution (2%) and acetic-sodium acetate buffer (pH [approximately equal to] 4.5).
Class-specific inhibitors of serineprotease (phenylmethylsulfonyl fluoride (PMSF) 4mM) and metalloprotease (1,10-phenanthroline
5mM) [13, 17, 27] were employed to determine the specific kinds of proteases produced.
Dehydration from tris[[beta]-diketonato]lanthanoids(III) on the 1,10-phenanthroline
adduct formation across lanthanoid series.
Zymograms were incubated in the presence of 5 mmol/L EDTA and 2 mmol/L 1,10-phenanthroline
for inhibition studies (31); activation of zymogens was achieved with 2 mmol/L p-aminophenyl-mercuric acetate (31).
(1989), which uses a 0.0375% solution of PCV (Acros Organics), together with a 15% hexamine buffer with pH adjusted to 6.2, and an iron interference reagent comprising 0.1% of 1,10-phenanthroline
and 0.5% ascorbic acid.
Ten millimoles of 1,10-phenanthroline
was added in the extraction buffer as a nuclease inhibitor and the hexadecyltrimethylammonium bromide step was omitted.