2,2'-bipyridine


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2,2′-bipyridine

[¦tü ¦tü·prīm ¦bī′pir·ə‚dēn]
(organic chemistry)
2,2′-dipyridyl
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Tetrahydrofuran (THF), methanol, ethanol, n-hexane, 1,4-dibromobutane, 2,2'-bipyridine (bpy), N,N-tetraethylthiuram disulfide (TD; Tokyo Kasei Organic Chemicals, Tokyo, Japan), silver nitrate (AgN[O.sub.3]), potassium thiocyanate (KCNS), hydrochloric acid (HCl) and copper(I) bromide (CuBr; Kanto Chemicals, Tokyo, Japan) were used as received.
For example, [bis(1,10-phenanthroline) L2copper(II)] (L = cis-5-norbornene-endo-2, 3-dicarboxylic acid; 2,2'-bipyridine; dicyanamide, adenine, and thymine) is well known for its numerous biological activities such as anti-Candida [21], antimycobacterial, and antimicrobial [23] activity.
Terzis, Reactions of 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) with yttrium(III) nitrate: preparation, X-ray crystal structures and spectroscopic characterization of the bis-bpy and bis-phen complexes, Transit.
This work details the synthesis of a series of isostructural lanthanide dicyanoaurates complexes containing the ancillary ligand 2,2'-bipyridine. Syntheses were carried out by reaction of Ln3+ triflate salts and potassium dicyanoaurate with 2,2'-bipyridine (bpy) resulting in the compound, [Ln(C10H8N2)(H2O)4(Au(CN)2)], (Ln=Tb and Gd).
In this study, the following complexes were used: sodium (2,2'-bipyridine)oxidobisperoxidovanadate(V) octahydrate, Na[VO[([O.sub.2]).sub.2](2,2'-bpy)] x 8[H.sub.2]O, marked as V (453.9 g/mol); bis(2,2'-bipyridine)oxidovanadium(IV) sulfate dihydrate, [VO(S[O.sub.4])(2,2'-bpy)] x 2[H.sub.2]O, marked as B (511.21 g/mol); and bis(4,4'-dimethyl-2,2'-bipyridine)oxidovanadium(IV) sulfate dihydrate, [VO[(4,4'-Me-2,2'-bpy).sub.2]]S[O.sub.4] x 2[H.sub.2]O marked as Bm (567.21 g/mol).
Cyano-metal complexes in acid solutions also act as linker moiety, for instance, Meyer and co-workers tailored [Na.sub.2][Fe(bpy)[(CN).sub.4]], (where bpy = 2,2'-bipyridine) to Ti[O.sub.2], through a single cyanide ligand with a C40 symmetry, as [Ti.sup.IV]-NC-[Fe.sup.II][(CN).sub.3].
The present investigation has been undertaken to fix the role of substrate [[Fe[(2,2'-bipyridine).sub.3]].sup.2+] in the [Ag.sup.+] catalysed oxidation by peroxodisulphate ([S.sub.2][O.sup.2-.sub.8]).
The addition complexes also exhibited additional peaks for the aromatic protons of the donorligands in the regions 7.24-7.64 (triphenylphosphine), 7.25-8.99 (1,10-phenanthroline), 7.29- 8.51 (pyridine), and 7.09-8.59 (2,2'-bipyridine).
Tris-chelated complexes of cobalt(III) and iron(II) with 1,10-phenanthroline and 2,2'-bipyridine," Journal of the American Chemical Society, vol.
The most common sensitizers are Ru(II) complexes based on 2,2'-bipyridine (bpy) ligands, such as cis-di(thiocyanato) bis(bpy4,4'-dicarboxylate)ruthenium(II) (N3 [9] and N719 [10]).
Oyman, ZO, Ming, W, van der Linde, R, van Gorkum, R, Bouwman, E, "Effect of [Mn(acac)[.sub.3]] and its Combination with 2,2'-Bipyridine on the Autoxidation and Oligomerisation of Ethyl Linoleate." Polymer, 46 1731-1738 (2005)
Relationship between structure attributes and observed electrogenerated chemiluminescence (ECL) activity of tertiary amines as potential analytes for the tris(2,2'-bipyridine)ruthenium (II) ECL reaction.